Control of solid-state dye-sensitized solar cell performance by block-copolymer-directed TiO2 synthesis

Docampo, P. , Guldin, S., Stefik, M., Tiwana, P., Orilall, M. C., Hüttner, S., Sai, H., Wiesner, U., Steiner, U. and Snaith, H. J. (2010) Control of solid-state dye-sensitized solar cell performance by block-copolymer-directed TiO2 synthesis. Advanced Functional Materials, 20(11), pp. 1787-1796. (doi: 10.1002/adfm.200902089)

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Abstract

Hybrid dye‐sensitized solar cells are typically composed of mesoporous titania (TiO2), light‐harvesting dyes, and organic molecular hole‐transporters. Correctly matching the electronic properties of the materials is critical to ensure efficient device operation. In this study, TiO2 is synthesized in a well‐defined morphological confinement that arises from the self‐assembly of a diblock copolymer—poly(isoprene‐b‐ethylene oxide) (PI‐b‐PEO). The crystallization environment, tuned by the inorganic (TiO2 mass) to organic (polymer) ratio, is shown to be a decisive factor in determining the distribution of sub‐bandgap electronic states and the associated electronic function in solid‐state dye‐sensitized solar cells. Interestingly, the tuning of the sub‐bandgap states does not appear to strongly influence the charge transport and recombination in the devices. However, increasing the depth and breadth of the density of sub‐bandgap states correlates well with an increase in photocurrent generation, suggesting that a high density of these sub‐bandgap states is critical for efficient photo‐induced electron transfer and charge separation.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Docampo, Dr Pablo
Authors: Docampo, P., Guldin, S., Stefik, M., Tiwana, P., Orilall, M. C., Hüttner, S., Sai, H., Wiesner, U., Steiner, U., and Snaith, H. J.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Advanced Functional Materials
Publisher:Wiley
ISSN:1616-301X
ISSN (Online):1616-3028
Published Online:21 April 2010

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