A large axial magnetic anisotropy in trigonal bipyramidal Fe(II)

Hay, M. A., Sarkar, A., Craig, G. A., Marriott, K. E.R., Wilson, C. , Rajaraman, G. and Murrie, M. (2020) A large axial magnetic anisotropy in trigonal bipyramidal Fe(II). Chemical Communications, 56(50), pp. 6826-6829. (doi: 10.1039/D0CC02382E) (PMID:32432288)

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Abstract

The first trigonal bipyramidal Fe(II) complex to display slow relaxation of magnetisation has been isolated, with this behaviour found to arise through a combination of a large magnetic anisotropy (D = -27.5 cm-1) and a pseudo-D3h symmetry at the Fe(II) centre, as investigated through ab initio and magnetic studies.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire and Craig, Dr Gavin and Hay, Ms Moya Anne and Murrie, Professor Mark and Marriott, Miss Katie
Authors: Hay, M. A., Sarkar, A., Craig, G. A., Marriott, K. E.R., Wilson, C., Rajaraman, G., and Murrie, M.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):364-548X
Published Online:06 May 2020
Copyright Holders:Copyright © 2020 The Royal Society of Chemistry
First Published:First published in Chemical Communications 56(50):6826-6829
Publisher Policy:Reproduced under a Creative Commons License

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
166734Mapping magnetic anistrophy: rational design of nanomagnets with increased blocking temperatures.Mark MurrieEngineering and Physical Sciences Research Council (EPSRC)EP/J018147/1Chemistry