Hay, M. A., Sarkar, A., Craig, G. A., Marriott, K. E.R., Wilson, C. , Rajaraman, G. and Murrie, M. (2020) A large axial magnetic anisotropy in trigonal bipyramidal Fe(II). Chemical Communications, 56(50), pp. 6826-6829. (doi: 10.1039/D0CC02382E) (PMID:32432288)
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Abstract
The first trigonal bipyramidal Fe(II) complex to display slow relaxation of magnetisation has been isolated, with this behaviour found to arise through a combination of a large magnetic anisotropy (D = -27.5 cm-1) and a pseudo-D3h symmetry at the Fe(II) centre, as investigated through ab initio and magnetic studies.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire and Craig, Dr Gavin and Marriott, Miss Katie and Hay, Ms Moya Anne and Murrie, Professor Mark |
Authors: | Hay, M. A., Sarkar, A., Craig, G. A., Marriott, K. E.R., Wilson, C., Rajaraman, G., and Murrie, M. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Chemical Communications |
Publisher: | Royal Society of Chemistry |
ISSN: | 1359-7345 |
ISSN (Online): | 364-548X |
Published Online: | 06 May 2020 |
Copyright Holders: | Copyright © 2020 The Royal Society of Chemistry |
First Published: | First published in Chemical Communications 56(50):6826-6829 |
Publisher Policy: | Reproduced under a Creative Commons License |
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