Bailey, P. J., Bell, N. L. , Gim, L. L., Yucheng, T., Funnell, N., White, F. and Parsons, S. (2011) “Twisted” scorpionates: synthesis of a tris(2-pyridonyl)borate (Thp) ligand; lessons in the requirements for successful B(L2D)3 type ligands. Chemical Communications, 47(42), pp. 11659-11661. (doi: 10.1039/C1CC14473A) (PMID:21959268)
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Abstract
The synthesis of a new charge-neutral zwitterionic tripodal borate ligand based on 2-hydroxypyridine is reported. (Dimethylaminopyridinium)tris(2-pyridonyl)borate, (DMAP)Thp, has been complexed to copper(I) chloride to give a pseudo-C3 symmetric complex. The propensity for this ligand and other flexible scorpionates to exhibit such helical chirality upon complexation is discussed.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Bell, Dr Nicola |
| Authors: | Bailey, P. J., Bell, N. L., Gim, L. L., Yucheng, T., Funnell, N., White, F., and Parsons, S. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 30 September 2011 |
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