Bailey, P. J., Bell, N. L. , Nichol, G. S., Parsons, S. and White, F. (2012) Insertion and substitution chemistry at the boron fourth position in charge-neutral zwitterionic tripodal tris(methimazolyl)borate ligands. Inorganic Chemistry, 51(6), pp. 3677-3689. (doi: 10.1021/ic202618p) (PMID:22376269)
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Abstract
A number of new charge-neutral zwitterionic tris(methimazolyl)borate ligands have been synthesized, either by substitution of the dimethylamine group in the adduct (dimethylamine)tris(methimazolyl)borane (1) or by insertion into its B–N(dimethylamine) bond by an unsaturated Lewis base. Two new anionic ligands, (thiocyanato)tris(methimazolyl)borate and (cyano)tris(methimazolyl)borate, have also been accessed by this method.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Bell, Dr Nicola |
| Authors: | Bailey, P. J., Bell, N. L., Nichol, G. S., Parsons, S., and White, F. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Inorganic Chemistry |
| Publisher: | American Chemical Society |
| ISSN: | 0020-1669 |
| ISSN (Online): | 1520-510X |
| Published Online: | 29 February 2012 |
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