Sol-gel coatings for subaquatic self-cleaning windows

Greer, A. , Moodie, D., Kerr, G. and Gadegaard, N. (2020) Sol-gel coatings for subaquatic self-cleaning windows. Crystals, 10(5), 375. (doi: 10.3390/cryst10050375)

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Abstract

Self-cleaning windows are well known for their ability to function with airborne pollutants, but there is a growing industry for semi-permanent subaquatic optical devices, where the performance of such windows should be considered. Here sol-gel technology is explored as a means of producing self-cleaning, subaquatic, sapphire windows. We demonstrate removal of marine bacteria and, in the worst-case contamination scenario, dead North Sea crude oil (API 35). This greasy contaminant was smeared across the windows to effectively reduce optical transmission strength to just 54%. The titania-based sol-gel-coated windows can restore transmission to within 10% of the clean value in less than one day, unlike standard sapphire windows, which lose 68% transmission following contamination and aquatic submergence over the same duration. A range of theories to enhance the self-cleaning performance of the sol-gel coating were explored, but none of the tested variables were able to provide any enhancement for subaquatic performance.

Item Type:Articles
Additional Information:Funding: The authors would like to acknowledge the funding provided by FMC Technologies Inc to carry out this research. AIMG was funded by EPSRC (EP/P505534/1) 63677.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Kerr, Dr Graham and Greer, Dr Andrew and Gadegaard, Professor Nikolaj
Creator Roles:
Gadegaard, N.Conceptualization, Methodology, Validation, Resources, Writing – review and editing, Supervision, Project administration
Kerr, G.Conceptualization, Resources, Project administration, Funding acquisition
Greer, A.Methodology, Validation, Formal analysis, Investigation, Data curation, Writing – original draft, Writing – review and editing, Visualization
Authors: Greer, A., Moodie, D., Kerr, G., and Gadegaard, N.
College/School:College of Science and Engineering > School of Engineering > Biomedical Engineering
Journal Name:Crystals
Publisher:MDPI
ISSN:2073-4352
ISSN (Online):2073-4352
Copyright Holders:Copyright © 2020 by the authors
First Published:First published in Crystals 10(5):375
Publisher Policy:Reproduced under a Creative Commons Licence

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
190262EPSRC Doctoral Training Grant 2010-14Mary Beth KneafseyEngineering and Physical Sciences Research Council (EPSRC)EP/P505534/1Research and Innovation Services