Solution-processed, indacenodithiophene-based, small-molecule organic field-effect transistors and solar cells

Liu, D., Xiao, M., Du, Z., Yan, Y., Han, L., Roy, V.A.L. , Sun, M., Zhu, W., Lee, C.S. and Yang, R. (2014) Solution-processed, indacenodithiophene-based, small-molecule organic field-effect transistors and solar cells. Journal of Materials Chemistry C, 2(36), pp. 7523-7530. (doi: 10.1039/c4tc00721b)

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Abstract

Two indacenodithiophene-based molecules with different side chains, BTIDT-C6 and BTIDT-OC12, have been designed and synthesized for solution-processed, small-molecule organic solar cells (OSCs) donor materials. By optimizing the side chains, the hole mobility of the materials is modulated, which has been proven by the organic field-effect transistor (OFET) performances. Solar cells based on BTIDT-C6 show a power conversion efficiency (PCE) of 4.83%. To the best of our knowledge, this is the first report about indacenodithiophene-based, solution-processed, small-molecule OFETs, and it is also one of the highest PCE reports for the indacenodithiophene-based, solution-processed, small-molecule OSCs. This report makes indacenodithiophene-based small molecules the third type of high-efficiency (5% PCE), solution-processed, small-molecule OSCs donor materials, in addition to benzodithiophene (BDT) and dithienosilole (DTS).

Item Type:Articles
Additional Information:The authors are deeply grateful to the National Natural Science Foundation of China (Project no. 21274134, 51173199, 21172187, 51211140346), the New Century Excellent Talents in University (NCET-11-0473), the Shandong Provincial Natural Science Foundation (ZR2011BZ007), the Hong Kong Scholar Program and Postdoctoral Science Foundation of China (XJ2012042, 2012T50630, 2013M530329), the Shenzhen Municipal Science and Technology Program (JCYJ20130401145617279) and the Qingdao Municipal Science and Technology Program (13-1-4-200-jch, 11-2-4-22-hz) for financial support.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Vellaisamy, Professor Roy
Authors: Liu, D., Xiao, M., Du, Z., Yan, Y., Han, L., Roy, V.A.L., Sun, M., Zhu, W., Lee, C.S., and Yang, R.
College/School:College of Science and Engineering > School of Engineering > Electronics and Nanoscale Engineering
Journal Name:Journal of Materials Chemistry C
Publisher:R S C Publications
ISSN:2050-7526
Published Online:14 July 2014

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