Sieber, R., Decurtins, S., Stoeckli-Evans, H., Wilson, C. , Yufit, D., Howard, J. A.K., Capelli, S. C. and Hauser, A. (2000) A Thermal Spin Transition in [Co(bpy)3][LiCr(ox)3] (ox=C2O42−; bpy=2,2′‐bipyridine). Chemistry: A European Journal, 6(2), pp. 361-368. (doi: 10.1002/(sici)1521-3765(20000117)6:2<361::aid-chem361>3.0.co;2-y)
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Abstract
Incorporation of [Co(bpy)3]2+ into the cavities of the three‐dimensional oxalate network structure in [Co(bpy)3][LiCr(ox)3] (see picture) produces chemical pressure that destabilises the normal high‐spin ground state 4T1 to such an extent that the [Co(bpy)3]2+ complex becomes a spin‐crossover complex. It shows a temperature‐dependent equilibrium between the 2E low‐spin and the 4T1 high‐spin states.
Item Type: | Articles |
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Additional Information: | This work was financially supported by the "Schweizerischer Nationalfonds", the "Fondation Ernst et Lucie Schmid-heiny", and the "Bundesamt fur Forschung und Wissenschaft" within a European Union TMR network. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire |
Authors: | Sieber, R., Decurtins, S., Stoeckli-Evans, H., Wilson, C., Yufit, D., Howard, J. A.K., Capelli, S. C., and Hauser, A. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Chemistry: A European Journal |
Publisher: | Wiley |
ISSN: | 0947-6539 |
ISSN (Online): | 1521-3765 |
Published Online: | 12 January 2000 |
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