A phenoxyl radical complex of copper(II)

Benisvy, L., Blake, A. J., Collison, D., Davies, E. S., Garner, C. D., McInnes, E. J.L., McMaster, J., Whittaker, G. and Wilson, C. (2001) A phenoxyl radical complex of copper(II). Chemical Communications, 2001(18), pp. 1824-1825. (doi:10.1039/b105186p)

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Abstract

A new N,O-bidentate pro-ligand (HL), [ML2] (M = Cu, Zn) and [CuL2][BF4] have been synthesised; [CuL2]·4DMF and [CuL2][BF4]·2CH2Cl2 have been crystallographically and spectroscopically characterised; these data indicate that [CuL2]+ cations are constituted as [Cu2+(L˙)(L−)]+ and involve the phenoxyl radical L˙.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire
Authors: Benisvy, L., Blake, A. J., Collison, D., Davies, E. S., Garner, C. D., McInnes, E. J.L., McMaster, J., Whittaker, G., and Wilson, C.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:03 September 2001

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