Unprecedented Seven- and Eight-Connected Lanthanide Coordination Networks

Long, D.-L. , Blake, A. J., Champness, N. R., Wilson, C. and Schröder, M. (2001) Unprecedented Seven- and Eight-Connected Lanthanide Coordination Networks. Angewandte Chemie (International Edition), 40(13), pp. 2443-2447. (doi:10.1002/1521-3773(20010702)40:13<2443::aid-anie2443>3.0.co;2-c) (PMID:29712301)

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Abstract

Eight‐coordinate metal‐ion nodes are linked through 4,4‐bipyridine‐N,N′‐dioxide (L) ligands to form the first examples of eight‐ and seven‐connected coordination networks. Thus, whereas [La(L)4](CF3SO3)3 adopts an eight‐connected body‐centered hypercubic CsCl‐like lattice (see picture), [La(L)4](BPh4)(ClO4)2 shows eight‐coordinate, but seven‐connected, nodes linked in an unprecedented 41762 topology.

Item Type:Articles
Additional Information:This work was supported by the Royal Society and the Engineering and Physical Sciences Research Council (Royal Society K. C. Wong and EPSRC postdoctoral fellowships to D.‐L.L.).
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire and Long, Dr Deliang
Authors: Long, D.-L., Blake, A. J., Champness, N. R., Wilson, C., and Schröder, M.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Publisher:Wiley
ISSN:1433-7851
ISSN (Online):1521-3773
Published Online:28 June 2001

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