Blake, A.J., Felloni, M., Hubberstey, P., Wilson, C. and Schröder, M. (2002) Triaqua(2,6-pyridinedicarboxylato)copper(II) at 150 K. Acta Crystallographica. Section E: Structure Reports Online, 58(2), m43-m46. (doi: 10.1107/s160053680102164x)
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Abstract
The asymmetric unit of the title compound, [Cu(C7H3NO4)(H2O)3], comprises a distorted tetragonally elongated octahedral copper(II) centre coordinated equatorially by a tridentate 2,6-pyridinedicarboxylate anion [Cu-N 1.9093 (14), and Cu-O 2.0368 (11) and 2.0397 (11) Å] and a strongly bound water molecule [Cu-O 1.9047 (12) Å] and axially by two weakly bound water molecules [Cu-O 2.3631 (12) and 2.4739 (12) Å]. The extended structure is based on a layered arrangement in which sheets of stacked molecular units are alternately linked by hydrogen-bonding and [pi]-[pi] stacking interactions.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire |
| Authors: | Blake, A.J., Felloni, M., Hubberstey, P., Wilson, C., and Schröder, M. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Acta Crystallographica. Section E: Structure Reports Online |
| Publisher: | International Union of Crystallography |
| ISSN: | 1600-5368 |
| Published Online: | 11 January 2002 |
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