Barnett, S.A., Blake, A.J., Champness, N.R. and Wilson, C. (2002) trans -Bis(acetonitrile)tetraaquacobalt(II) dinitrate at 150 K. Acta Crystallographica. Section E: Structure Reports Online, 58(8), m444-m446. (doi: 10.1107/s1600536802012850)
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Abstract
In the title compound, [Co(CH3CN)2(H2O)4](NO3)2, the CoII cations occupy crystallographic inversion centres and adopt a distorted octahedral coordination geometry, with trans-disposed acetonitrile ligands. Extensive hydrogen-bonding interactions between the coordinated water ligands and the nitrate counter-anions lead to the formation of a three-dimensional framework. There are substantial differences between the structure of the title compound at 150 K and the previously reported structure at 293 K.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire |
| Authors: | Barnett, S.A., Blake, A.J., Champness, N.R., and Wilson, C. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Acta Crystallographica. Section E: Structure Reports Online |
| Publisher: | International Union of Crystallography |
| ISSN: | 1600-5368 |
| Published Online: | 25 July 2002 |
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