Wang, Q., Blake, A. J., Davies, E. S., McInnes, E. J.L., Wilson, C. and Schröder, M. (2003) Structure and electronic properties of an asymmetric thiolate-bridged binuclear complex: a model for the active site of acetyl CoA synthase. Chemical Communications, 2003(24), pp. 3012-3013. (doi: 10.1039/B310183E) (PMID:14703833)
Full text not currently available from Enlighten.
Abstract
The asymmetric binuclear complex [(dppe)Ni(μ-‘S, S’)Ni(L)](PF6)2 [L = (N, N′-diethyl-3,7-diazanonane-1,9-dithiolato)2−] shows a reversible one-electron reduction to afford a mixed-valent Ni(II)·Ni(I) species; the reduced complex has been characterised by EPR spectroscopy and mimics the redox active Nip site in the active A-cluster of acetyl coenzyme A synthase.
Item Type: | Articles |
---|---|
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire |
Authors: | Wang, Q., Blake, A. J., Davies, E. S., McInnes, E. J.L., Wilson, C., and Schröder, M. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Chemical Communications |
Publisher: | Royal Society of Chemistry |
ISSN: | 1359-7345 |
ISSN (Online): | 1364-548X |
Published Online: | 03 November 2003 |
University Staff: Request a correction | Enlighten Editors: Update this record