Anionic amido N-heterocyclic carbenes: synthesis of covalently tethered lanthanide–carbene complexes

Arnold, P. L., Mungur, S. A., Blake, A. J. and Wilson, C. (2003) Anionic amido N-heterocyclic carbenes: synthesis of covalently tethered lanthanide–carbene complexes. Angewandte Chemie (International Edition), 42(48), pp. 5981-5984. (doi:10.1002/anie.200352710) (PMID:14679548)

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Abstract

Organolanthanides with amido‐tethered N‐heterocyclic carbenes: a new bidentate ligand that tethers an N‐heterocyclic carbene group to a trivalent lanthanide complex (samarium, depicted, N′′=N(SiMe3)2; or yttrium) affords the first organolanthanide amido–carbene complexes and an opportunity to explore the strength and reactivity of the early metal–N‐heterocyclic carbene fragment.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire
Authors: Arnold, P. L., Mungur, S. A., Blake, A. J., and Wilson, C.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Publisher:Wiley
ISSN:1433-7851
ISSN (Online):1521-3773
Published Online:10 December 2003

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