Arnold, P. L., Rodden, M. and Wilson, C. (2005) Thermally stable potassium N-heterocyclic carbene complexes with alkoxide ligands, and a polymeric crystal structure with distorted, bridging carbenes. Chemical Communications, 2005(13), pp. 1743-1745. (doi: 10.1039/B418302A) (PMID:15791318)
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Abstract
Alkoxide-functionalised N-heterocyclic carbenes (NHCs) stabilise the potassium-imidazole-2-ylidene fragment against 1,2 alkyl rearrangement reactions; this allows the first structural characterisation of a potassium NHC complex, which reveals distorted and unusual bonding interactions between the imidazole ring and the potassium cation.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire |
| Authors: | Arnold, P. L., Rodden, M., and Wilson, C. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 03 February 2005 |
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