Metal-directed ring-expansion in Schiff-base polypyrrolic macrocycles

Givaja, G., Blake, A. J., Wilson, C. , Schröder, M. and Love, J. B. (2005) Metal-directed ring-expansion in Schiff-base polypyrrolic macrocycles. Chemical Communications, 2005(35), pp. 4423-4425. (doi: 10.1039/B507729J) (PMID:16136238)

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Abstract

The reaction between a [2 + 2] Schiff-base porphyrin analogue and zinc acetate results in the unusual formation of an enlarged [3 + 3] macrocycle that is stabilised by metal coordination and intramolecular hydrogen-bonding interactions.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire
Authors: Givaja, G., Blake, A. J., Wilson, C., Schröder, M., and Love, J. B.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:29 July 2005

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