(±)- exo -2-Hydroxy-5-oxo-4,8-dioxatricyclo[ 3,7 ]nonane-9- exo -carboxylic acid

Sadeghi-Khomami, A., Thomas, N.R. and Wilson, C. (2006) (±)- exo -2-Hydroxy-5-oxo-4,8-dioxatricyclo[ 3,7 ]nonane-9- exo -carboxylic acid. Acta Crystallographica. Section E: Structure Reports Online, 62(9), o3759-o3761. (doi: 10.1107/s1600536806030649)

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The title compound, C8H9NO5, was prepared as a by-product in synthetic efforts to prepare a carbasugar analogue of a putative inter­mediate, viz. (±)-6-hydroxy­methyl-7-oxa­bicyclo­[2.2.1]hept-2-exo-3-endo-diol, in the uridine diphos­phate-galactopyran­ose mutase-catalysed reaction. The structure shows extensive hydrogen bonding involving N-H...O and O-H...O as well as C-H...O inter­actions.

Item Type:Articles
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire
Authors: Sadeghi-Khomami, A., Thomas, N.R., and Wilson, C.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Acta Crystallographica. Section E: Structure Reports Online
Publisher:International Union of Crystallography

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