Casely, I. J., Liddle, S. T., Blake, A. J., Wilson, C. and Arnold, P. L. (2007) Tetravalent cerium carbene complexes. Chemical Communications, 2007(47), pp. 5037-5039. (doi: 10.1039/B713041D) (PMID:18049745)
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Abstract
The tetravalent organometallic cerium complex [CeL4] is readily accessible from the oxidation of the trivalent [CeL3], L = a bidentate N-heterocyclic carbene alkoxide ligand, [C{(NPri)CHCHN}CH2CMe2O]. The [CeL4] complex should behave like the [UL4] analogue, but the two complexes show significantly different structures, highlighting the differences between 4f and 5f metals.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire |
Authors: | Casely, I. J., Liddle, S. T., Blake, A. J., Wilson, C., and Arnold, P. L. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Chemical Communications |
Publisher: | Royal Society of Chemistry |
ISSN: | 1359-7345 |
ISSN (Online): | 1364-548X |
Published Online: | 09 October 2007 |
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