Competition between planar and central chiral control elements in nucleophilic addition to ferrocenyl imine derivatives

Joly, K. M., Wilson, C. , Blake, A. .J., Tucker, J. H.R. and Moody, C. J..J. (2008) Competition between planar and central chiral control elements in nucleophilic addition to ferrocenyl imine derivatives. Chemical Communications, 41, pp. 5191-5193. (doi:10.1039/b808045c) (PMID:18956065)

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Abstract

Planar chirality associated with the ferrocene in ferrocenyl oximes and hydrazones bearing chiral auxiliaries effectively competes with or overrides the normally excellent stereocontrol afforded by the auxiliary in determining the diastereoselectivity of addition to the C=N bond.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire
Authors: Joly, K. M., Wilson, C., Blake, A. .J., Tucker, J. H.R., and Moody, C. J..J.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Publisher:Royal Society of Chemistry
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:12 September 2008

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