Bis(1-carbamimidoyl-2-ethylisourea)copper(II) bis(perchlorate)

Meenongwa, A., Chaveerach, U., Wilson, C. and Blake, A.J. (2009) Bis(1-carbamimidoyl-2-ethylisourea)copper(II) bis(perchlorate). Acta Crystallographica Section E Structural Reports Online, E65, m1171. (doi:10.1107/s1600536809034965) (PMID:21577707) (PMCID:PMC2970167)

[img]
Preview
Text
192978.pdf - Published Version
Available under License Creative Commons Attribution.

367kB

Abstract

The title complex, [Cu(C4H10N4O)2](ClO4)2 or [Cu(L1e)2](ClO4)2, where L1e is 1-carbamimidoyl-2-ethyl­isourea, was obtained from the ethano­lysis reaction of 2-cyano­guanidine and copper(II) perchlorate hexa­hydrate in a 2:1 molar ratio. The two bidentate L1e ligands are coordinated to the CuII center through N-donor atoms, leading to the CuN4 chromophore. The CuII environment is slightly distorted square-planar, with a dihedral angle of 5.17 (6)° between the two six-membered chelate rings. One of the ClO4- anions is disordered over two positions in a 0.6:0.4 ratio.

Item Type:Articles
Additional Information:Supported by funding from the Thailand Research Fund (TRF), the Office of the National Research Council of Thailand (NRCT), the Center of Excellence for Innovation in Chemistry (PERCH-CIC) and the Development and Promotion of Science and Technology Talents Oroject (DPST).
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire
Authors: Meenongwa, A., Chaveerach, U., Wilson, C., and Blake, A.J.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Acta Crystallographica Section E Structural Reports Online
Publisher:International Union of Crystallography
ISSN:1600-5368
ISSN (Online):1600-5368
Copyright Holders:Copyright © 2009 Meenongwa et al.
First Published:First published in Acta Crystallogr Sect E Struct Rep Online 65(Pt 10): m1171
Publisher Policy:Reproduced under a Creative Commons License

University Staff: Request a correction | Enlighten Editors: Update this record