Meenongwa, A., Chaveerach, U., Wilson, C. and Blake, A.J. (2009) Bis(1-carbamimidoyl-2-ethylisourea)copper(II) bis(perchlorate). Acta Crystallographica Section E Structural Reports Online, E65, m1171. (doi: 10.1107/s1600536809034965) (PMID:21577707) (PMCID:PMC2970167)
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Abstract
The title complex, [Cu(C4H10N4O)2](ClO4)2 or [Cu(L1e)2](ClO4)2, where L1e is 1-carbamimidoyl-2-ethylisourea, was obtained from the ethanolysis reaction of 2-cyanoguanidine and copper(II) perchlorate hexahydrate in a 2:1 molar ratio. The two bidentate L1e ligands are coordinated to the CuII center through N-donor atoms, leading to the CuN4 chromophore. The CuII environment is slightly distorted square-planar, with a dihedral angle of 5.17 (6)° between the two six-membered chelate rings. One of the ClO4- anions is disordered over two positions in a 0.6:0.4 ratio.
Item Type: | Articles |
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Additional Information: | Supported by funding from the Thailand Research Fund (TRF), the Office of the National Research Council of Thailand (NRCT), the Center of Excellence for Innovation in Chemistry (PERCH-CIC) and the Development and Promotion of Science and Technology Talents Oroject (DPST). |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire |
Authors: | Meenongwa, A., Chaveerach, U., Wilson, C., and Blake, A.J. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Acta Crystallographica Section E Structural Reports Online |
Publisher: | International Union of Crystallography |
ISSN: | 1600-5368 |
ISSN (Online): | 1600-5368 |
Copyright Holders: | Copyright © 2009 Meenongwa et al. |
First Published: | First published in Acta Crystallogr Sect E Struct Rep Online 65(Pt 10): m1171 |
Publisher Policy: | Reproduced under a Creative Commons License |
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