Tan, A. L., Blake, A. J., Davies, E. S., Wilson, C. and Garner, C. D. (2011) A radical pathway to synthesise Mo and W dithiolene complexes. Chemical Communications, 47(3), pp. 953-954. (doi: 10.1039/C0CC03756G) (PMID:21076759)
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Abstract
A new method has been developed to synthesise bis η5-cyclopentadienyl dithiolene complexes of molybdenum and tungsten. This procedure involves the in situthermolysis of the azo compounds, 2,2′-azobisisobutyronitrile (AIBN) or 1,1′-azobiscyclohexanecarbonitrile (ACCN) (R′2N2, R′ = CMe2CN or C6H10CN, respectively), which initiates a reaction between [Cp2M(S4)] (M = Mo or W) and an alkyne (HC2R, R = Ph, 2-pyridyl or 2-quinoxalinyl) and produce the corresponding [Cp2M(S2C2RR′)] compound.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire |
| Authors: | Tan, A. L., Blake, A. J., Davies, E. S., Wilson, C., and Garner, C. D. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 15 November 2010 |
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