Cao, Q., Kumru, B., Antonietti, M. and Schmidt, B. V.K.J. (2019) Grafting polymers onto carbon nitride via visible-light-induced photofunctionalization. Macromolecules, 52(13), pp. 4989-4996. (doi: 10.1021/acs.macromol.9b00894)
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Abstract
Metal-free graphitic carbon nitride (g-CN) has attracted significant attention recently due to its multiple applications, such as photocatalysis, energy storage and conversion, and biomaterials, albeit formation of g-CN films is challenging. Herein, a “grafting to” route to graft polymer brushes onto g-CN via visible-light irradiation is described. Afterward, g-CN/polymer films can be obtained through spin coating on glass substrates. As such, the present material provides an improved process toward further application of g-CN in thin films. Moreover, an improved dispersibility in organic solvent was realized after grafting and functional groups (such as epoxides) were introduced to g-CN. Subsequently, the epoxy groups were utilized for further functionalization to adjust the surface polarity.
Item Type: | Articles |
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Additional Information: | The authors are grateful for funding from the Max-Planck Society. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Schmidt, Dr Bernhard |
Authors: | Cao, Q., Kumru, B., Antonietti, M., and Schmidt, B. V.K.J. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Macromolecules |
Publisher: | American Chemical Society |
ISSN: | 0024-9297 |
ISSN (Online): | 1520-5835 |
Published Online: | 20 June 2019 |
Copyright Holders: | Copyright © 2019 American Chemical Society |
First Published: | First published in Macromolecules 52(13): 4989-4996 |
Publisher Policy: | Reproduced under a Creative Commons License |
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