Janusson, E. , de Kler, N., Vilà-Nadal, L. , Long, D.-L. and Cronin, L. (2019) Synthesis of polyoxometalate clusters using carbohydrates as reducing agents leads to isomer-selection. Chemical Communications, 55(41), pp. 5797-5800. (doi: 10.1039/C9CC02361E) (PMID:31041957)
|
Text
186345.pdf - Published Version Available under License Creative Commons Attribution Non-commercial. 2MB |
Abstract
By using sugars as the reducing agents, we demonstrate that it is possible to control the self-assembly of polyoxomolybdates through selective preparation of a single heteropolyanion isomer. D-(−)-Fructose has been proved to be an effective reducing sugar compared to the chemically similar carbohydrate D-(+)-glucose. The gentle reduction results in favourable formation of the Wells–Dawson type gamma isomer in 6-fold reduced form at room temperature.
| Item Type: | Articles |
|---|---|
| Additional Information: | A correction to this article is available at http://dx.doi.org/10.1039/C9CC90217A. |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Vila-Nadal, Dr Laia and Janusson, Dr Eric and de Kler, Noel and Long, Dr Deliang and Cronin, Professor Lee |
| Authors: | Janusson, E., de Kler, N., Vilà-Nadal, L., Long, D.-L., and Cronin, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 26 April 2019 |
| Copyright Holders: | Copyright © 2019 The Royal Society of Chemistry |
| First Published: | First published in Chemical Communications 55:5797-5800 |
| Publisher Policy: | Reproduced under a Creative Commons License |
| Related URLs: |
University Staff: Request a correction | Enlighten Editors: Update this record
Altmetric
Altmetric