Canaj, A. B. , Singh, M. K., Regincos Marti, E., Damjanović, M., Wilson, C. , Céspedes, O., Wernsdorfer, W., Rajaraman, G. and Murrie, M. (2019) Boosting axiality in stable high-coordinate Dy(III) single-molecule magnets. Chemical Communications, 55(42), pp. 5950-5953. (doi: 10.1039/C9CC00965E) (PMID:31049540)
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Abstract
A new nine-coordinate, air-stable Dy(III) single-ion magnet has been successfully isolated. Our in silico studies demonstrate that through carefully modulating the ligand electronics, the axiality can be boosted to generate Ucal barriers of over 600 K.
| Item Type: | Articles |
|---|---|
| Additional Information: | G. R. thanks the SERB (EMR/2014/00024) for funding. MKS thanks IIT Bombay for a fellowship. |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire and Tsanai, Dr Angelos and Regincos Marti, Miss Emma and Murrie, Professor Mark |
| Authors: | Canaj, A. B., Singh, M. K., Regincos Marti, E., Damjanović, M., Wilson, C., Céspedes, O., Wernsdorfer, W., Rajaraman, G., and Murrie, M. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 29 April 2019 |
| Copyright Holders: | Copyright © 2019 The Royal Society of Chemistry |
| First Published: | First published in Chemical Communications 55(42): 5950-5953 |
| Publisher Policy: | Reproduced under a Creative Commons License |
| Data DOI: | 10.5525/gla.researchdata.789 |
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