McGuire, J., Wilson, B., McAllister, J., Miras, H. N. , Wilson, C. , Sproules, S. and Farnaby, J. H. (2019) Molecular and electronic structure of the dithiooxalato radical ligand stabilised by rare earth coordination. Dalton Transactions, 48, pp. 5491-5495. (doi: 10.1039/C9DT00688E) (PMID:30892339)
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Abstract
Heterometallic rare earth transition metal compounds of dithioxalate (dto)2–, [NiII{(dto)LnIIITp2}2] (Ln = Y (1), Gd (2); Tp = hydrotris(pyrazol-1-yl)borate) were synthesised. The Lewis acidic rare earth ions are bound to the dioxolene and chemical reduction of 1 and 2 with cobaltocene yielded [CoCp2]+[NiII{(dto)LnIIITp2}2]˙− Ln = Y (3), Gd (4). The reduction is ligand-based and 3 and 4 are the first examples of both molecular and electronic structural characterisation of the dithiooxalato radical (dto)3˙−.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Sproules, Dr Stephen and Farnaby, Dr Joy and Moiras, Professor Haralampos and Wilson, Dr Claire and McAllister, Mr James and Wilson, Mr Bradley and McGuire, Mr Jake |
| Authors: | McGuire, J., Wilson, B., McAllister, J., Miras, H. N., Wilson, C., Sproules, S., and Farnaby, J. H. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Dalton Transactions |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1477-9226 |
| ISSN (Online): | 1477-9234 |
| Published Online: | 13 March 2019 |
| Copyright Holders: | Copyright © 2019 The Royal Society of Chemistry |
| First Published: | First published in Dalton Transactions 48:5491-5495 |
| Publisher Policy: | Reproduced under a Creative Commons License |
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