Sproules, S. (2019) Comment on “Stabilization of low-valent iron(I) in a high-valent vanadium(V) oxide cluster”. Angewandte Chemie (International Edition), 58(30), pp. 10043-10047. (doi: 10.1002/anie.201811125) (PMID:31267608)
|
Text
173921.pdf - Accepted Version 967kB | |
|
Text
173921Supp.pdf - Supplemental Material 1MB |
Abstract
A recent Communication in this journal reported the stabilization of low‐valent iron(I) in a fully oxidized polyoxovanadate. With no ligand‐field argument to support such an assignment, a re‐evaluation of the data accompanied by detailed computational analysis reveals the redox chemistry is localized to the polyoxovanadate, and when reduced, instigates a spin transition at iron.
Item Type: | Articles |
---|---|
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Sproules, Dr Stephen |
Authors: | Sproules, S. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Angewandte Chemie (International Edition) |
Publisher: | Wiley |
ISSN: | 1433-7851 |
ISSN (Online): | 1521-3773 |
Published Online: | 03 July 2019 |
Copyright Holders: | Copyright © 2019 Wiley-VCH Verlag GmbH and Co. KGaA |
First Published: | First published in Angewandte Chemie (International Edition) 58(30): 10043-10047 |
Publisher Policy: | Reproduced in accordance with the publisher copyright policy |
University Staff: Request a correction | Enlighten Editors: Update this record