Frampton, C. S., Gall, J. H. and MacNicol, D. D. (2017) Total CCl4 guest alignment in a quasiracemic clathrate closely related to Dianin's compound. CrystEngComm, 19(38), pp. 5703-5706. (doi: 10.1039/c7ce01275f)
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Abstract
Single crystal X-ray analysis at 100 K reveals that in the trigonal CCl4quasiracemic clathrate, space group R3, formed from host components S-(−)-Dianin's compound and its (+)-2R,4R 2-nor methyl analogue there is an unprecedented complete ordering of a C–Cl bond of the guest with respect to the c-axial direction. In this clathrate and that formed from the (+)-2R,4R and (+)-2R,4S epimers the participation of an unexpected host conformation is reported for the first time.
Item Type: | Articles |
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Additional Information: | Financial support from the Malaysia HIR MOHE, Grant No. F000009-2100. |
Keywords: | General materials science, general chemistry, condensed matter physics. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Gall, Mr Jim and MacNicol, Dr David |
Authors: | Frampton, C. S., Gall, J. H., and MacNicol, D. D. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | CrystEngComm |
Publisher: | Royal Society of Chemistry (RSC) |
ISSN: | 1466-8033 |
ISSN (Online): | 1466-8033 |
Published Online: | 07 August 2017 |
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