Henry, M. C., Sutherland, A. and Mostafa, M. A.B. (2017) Recent advances in transition-metal-catalyzed, directed Aryl C-H/N-H cross coupling reactions. Synthesis, 49(20), pp. 4586-4598. (doi: 10.1055/s-0036-1588536)
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Abstract
Amination and amidation of aryl compounds using a transition-metal-catalyzed cross-coupling reaction typically involves prefunctionalization or preoxidation of either partner. In recent years, a new class of transition-metal-catalyzed cross-dehydrogenative coupling reaction has been developed for the direct formation of aryl C–N bonds. This short review highlights the substantial progress made for ortho-C–N bond formation via transition-metal-catalyzed chelation-directed aryl C–H activation and gives an overview of the challenges that remain for directed meta- and para-selective reactions.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Henry, Mr Martyn and Mostafa, Mohamed and Sutherland, Professor Andrew |
| Authors: | Henry, M. C., Sutherland, A., and Mostafa, M. A.B. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Synthesis |
| Publisher: | Georg Thieme Verlag |
| ISSN: | 0039-7881 |
| ISSN (Online): | 1437-210X |
| Published Online: | 28 August 2017 |
| Copyright Holders: | Copyright © 2017 The Authors |
| First Published: | First published in Synthesis 49(20): 4586-4598 |
| Publisher Policy: | Reproduced under a Creative Commons License |
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