Cooper, A., Mackenzie, R. K., MacNicol, D. D. and Rycroft, D. S. (1980) Internal rotation in a guest molecule complexed with β-cyclodextrin in deuterium oxide solution. Journal of Chemical Research, Synopses(3), pp. 120-121.
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Abstract
The cyclodextrins have attracted much attention as enzyme active-site models. These torus-shaped molecules, possessing a central lipophilic cavity for guest inclusion, are made up of α-1,4-linked D-glucopyranose units, α-, β-, and γ-cyclodextrin (α-, β-, and γ-CD) comprising 6, 7, and 8 units, respectively. We now report the first example of the catalysis of a degenerate exchange process for a molecule accommodated in a cyclodextrin void. Internal rotation in N,N-dimethyl-p-nitrobenzamide (I) complexed by β-CD in D2O was selected for detailed study.
| Item Type: | Articles |
|---|---|
| Keywords: | NMR spectroscopy. |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Rycroft, Dr David and Mackenzie, Dr Roger and MacNicol, Dr David and Cooper, Professor Alan |
| Authors: | Cooper, A., Mackenzie, R. K., MacNicol, D. D., and Rycroft, D. S. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Journal of Chemical Research, Synopses |
| Publisher: | The Chemical Society |
| ISSN: | 0308-2342 |
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