Aminolysis reactions of tungsten hexafluoride: N-alkylimidofluorotungstates(VI)

Chambers, O. R., Rycroft, D. S., Sharp, D. W.A. and Winfield, J. M. (1976) Aminolysis reactions of tungsten hexafluoride: N-alkylimidofluorotungstates(VI). Inorganic and Nuclear Chemistry Letters, 12(7), pp. 559-561. (doi:10.1016/0020-1650(76)80022-0)

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Abstract

The ability of tungsten hexafluoride to behave as a Lewis acid is well documented (1,2), and the resulting complexes are formulated from their n.m.r. spectra as molecular species (2). An adduct, WF6・3MeNH2, has been described (1), but we now show that WF6 undergoes aminolysis with primary amines RNH2 (R = Me, Et, Bun, and But) and with methyl(trimethylsilyl)amine to give products containing R–N–WVI groups.

Item Type:Articles
Keywords:NMR spectroscopy.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Winfield, Professor John and Rycroft, Dr David
Authors: Chambers, O. R., Rycroft, D. S., Sharp, D. W.A., and Winfield, J. M.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Inorganic and Nuclear Chemistry Letters
Journal Abbr.:Inorg. Nucl. Chem. Letters
Publisher:Pergamon Press
ISSN:0020-1650

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