Chambers, O. R., Rycroft, D. S., Sharp, D. W.A. and Winfield, J. M. (1976) Aminolysis reactions of tungsten hexafluoride: N-alkylimidofluorotungstates(VI). Inorganic and Nuclear Chemistry Letters, 12(7), pp. 559-561. (doi: 10.1016/0020-1650(76)80022-0)
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Abstract
The ability of tungsten hexafluoride to behave as a Lewis acid is well documented (1,2), and the resulting complexes are formulated from their n.m.r. spectra as molecular species (2). An adduct, WF<sub>6</sub>・3MeNH<sub>2</sub>, has been described (1), but we now show that WF<sub>6</sub> undergoes aminolysis with primary amines RNH<sub>2</sub> (R = Me, Et, Bu<sup><i>n</i></sup>, and Bu<sup><i>t</i></sup>) and with methyl(trimethylsilyl)amine to give products containing R–N–W<sup>VI</sup> groups.
Item Type: | Articles |
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Keywords: | NMR spectroscopy. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Winfield, Professor John and Rycroft, Dr David |
Authors: | Chambers, O. R., Rycroft, D. S., Sharp, D. W.A., and Winfield, J. M. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Inorganic and Nuclear Chemistry Letters |
Journal Abbr.: | Inorg. Nucl. Chem. Letters |
Publisher: | Pergamon Press |
ISSN: | 0020-1650 |
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