Harvey, D. A., Keat, R., Keith, A. N., Muir, K. W. and Rycroft, D. S. (1979) Synthesis and structures of isomeric diphenylphosphinoamino-substituted cyclodiphosph(III)azanes. Inorganica Chimica Acta, 34, L201-L202. (doi: 10.1016/S0020-1693(00)94634-6)
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Abstract
The chemistry of the cyclodiphosph(III)azanes (1) (R = alkylamino, alkoxy ; R' = alkyl, aryl, Me3Si) has recently formed the subject of several investigations, with the effects of geometrical isomerism and the relationship with the phosph(III)azenes, RP=NR', receiving special attention. So far, only relatively simple amino- or silylamino-derivatives have been obtained, but we have now synthesized a diphenylphosphino-derivative (2), which is a tetraphosphine, and examined its solution and solid-state structure.
| Item Type: | Articles |
|---|---|
| Keywords: | Phosphorus chemistry, NMR spectroscopy. |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Muir, Dr Kenneth and Rycroft, Dr David |
| Authors: | Harvey, D. A., Keat, R., Keith, A. N., Muir, K. W., and Rycroft, D. S. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Inorganica Chimica Acta |
| Publisher: | Elsevier |
| ISSN: | 0020-1693 |
| ISSN (Online): | 1873-3255 |
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