Anderson, G. K., Cross, R. J. and Rycroft, D. S. (1979) Carbon-13 n.m.r. spectra of carbonyl and acyl complexes of platinum(II). Journal of Chemical Research(4), (S) 120; (M) 1601-1609.
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Abstract
We report 13C n.m.r. data for the carbonyl carbon atoms of 28 electroneutral carbonyl complexes of platinum(II), prepared from enriched 13CO. The compounds include all three isomers of [PtClPh(CO)L] (L = Et3P, PhMe2P, Ph2MeP, or Ph3P) and several examples each of [PtX2(CO)L] and that isomer of [PtXR(CO)L] with L and R trans (R = Me, Et, Ph, or CH2Ph). The observed variations in both chemical shifts and 195Pt—13C coupling constants are compared with published data on related, mainly anionic or cationic, carbonyl complexes.
Item Type: | Articles |
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Keywords: | Organometallic chemistry, NMR spectroscopy. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Rycroft, Dr David |
Authors: | Anderson, G. K., Cross, R. J., and Rycroft, D. S. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Journal of Chemical Research |
Publisher: | The Chemical Society |
ISSN: | 0308-2342 |
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