Carbon-13 n.m.r. spectra of carbonyl and acyl complexes of platinum(II)

Anderson, G. K., Cross, R. J. and Rycroft, D. S. (1979) Carbon-13 n.m.r. spectra of carbonyl and acyl complexes of platinum(II). Journal of Chemical Research(4), (S) 120; (M) 1601-1609.

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We report 13C n.m.r. data for the carbonyl carbon atoms of 28 electroneutral carbonyl complexes of platinum(II), prepared from enriched 13CO. The compounds include all three isomers of [PtClPh(CO)L] (L = Et3P, PhMe2P, Ph2MeP, or Ph3P) and several examples each of [PtX2(CO)L] and that isomer of [PtXR(CO)L] with L and R trans (R = Me, Et, Ph, or CH2Ph). The observed variations in both chemical shifts and 195Pt—13C coupling constants are compared with published data on related, mainly anionic or cationic, carbonyl complexes.

Item Type:Articles
Keywords:Organometallic chemistry, NMR spectroscopy.
Glasgow Author(s) Enlighten ID:Rycroft, Dr David
Authors: Anderson, G. K., Cross, R. J., and Rycroft, D. S.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of Chemical Research
Publisher:The Chemical Society

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