Brown, A. M., Rycroft, D. S. and Robins, D. J. (1991) Incorporation of the enantiomeric [1-2H]cadaverines into the quinolizidine alkaloid (–)-anagyrine in Anagyris foetida. Journal of the Chemical Society: Perkin Transactions 1, 10, pp. 2353-2355. (doi: 10.1039/P19910002353)
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Abstract
The labelling patterns in (–)-anagyrine 13 derived biosynthetically from (R)- and (S)-[1-2H]cadaverine 5 and 6, respectively, in Anagyris foetida have been established by 2H NMR spectroscopy. Comparison of the composite labelling pattern 14 with that 11 published for (+)-sparteine has distinguished between two possible pathways for conversion of a tetracyclic intermediate into (–)-anagyrine.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Rycroft, Dr David and Robins, Prof David |
| Authors: | Brown, A. M., Rycroft, D. S., and Robins, D. J. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Journal of the Chemical Society: Perkin Transactions 1 |
| Journal Abbr.: | J. Chem. Soc., Perkin Trans. 1 |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 0300-922X |
| ISSN (Online): | 2050-8255 |
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