Barron, L.D. (1971) Electric quadrupole contributions to the optical activity of crystalline transition metal complexes. Molecular Physics, 21(2), pp. 241-246. (doi: 10.1080/00268977100101381)
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Abstract
It is shown that the circular dichroism data from crystalline transition metal complexes of D 3 symmetry provides evidence for electric dipole-electric quadrupole contributions to the optical activity, as distinct from the usual electric dipole-magnetic dipole mechanism. Specifically, in 2[(+)-Co(en)3Cl3].NaCl.6H20 the 1A1→1E(T2g) transition, which is electric quadrupole allowed and magnetic dipole forbidden in the parent Oh complex, and the high frequency charge-transfer transitions of E symmetry, could provide significant electric quadrupole contributions to the circular dichroism. The electric quadrupole rotational strength obeys the Condon sum rule.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Barron, Professor Laurence |
| Authors: | Barron, L.D. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Molecular Physics |
| Publisher: | Taylor & Francis |
| ISSN: | 0026-8976 |
| ISSN (Online): | 1362-3028 |
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