A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

Heras Ojea, M. J., Lorusso, G., Craig, G. A., Wilson, C. , Evangelisti, M. and Murrie, M. (2017) A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring. Chemical Communications, 53(35), pp. 4799-4802. (doi: 10.1039/C7CC02243C) (PMID:28405656)

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The adiabatic temperature change of the star-shaped {CoIII3GdIII3} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions.

Item Type:Articles
Glasgow Author(s) Enlighten ID:Wilson, Dr Claire and Craig, Dr Gavin and Murrie, Professor Mark and Heras Ojea, Miss Maria Jose
Authors: Heras Ojea, M. J., Lorusso, G., Craig, G. A., Wilson, C., Evangelisti, M., and Murrie, M.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Publisher:Royal Society of Chemistry
ISSN (Online):1364-548X
Published Online:13 April 2017
Copyright Holders:Copyright © 2017 The Royal Society of Chemistry
First Published:First published in Chemical Communications 53(35):4799-4802
Publisher Policy:Reproduced under a Creative Commons License

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
555881Atom-by-atom control for the targeted chemical synthesis of heterometallic molecular nanomagnetsMark MurrieEngineering & Physical Sciences Research Council (EPSRC)EP/I027203/1CHEM - CHEMISTRY