Barron, L. D. (1977) Raman optical activity of simple chiral molecules; methyl and trifluoromethyl asymmetric deformations. Journal of the Chemical Society: Perkin Transactions 2, 1977(13), pp. 1790-1794. (doi: 10.1039/P29770001790)
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Abstract
Raman circular intensity differential spectra between 80 and 2 000 cm–1 of (–)-1-phenylethylamine, (+)-1-phenylethanol, (+)-2,2,2-trifluoro-1-phenylethanol, (+)-1-p-bromophenylethylamine, and (–)-N-benzyl-1phenylethylamine are presented, and several stereochemical correlations are pointed out. The spectrum of the p-bromo-species indicates that the previously reported identification of a couplet with the methyl asymmetric deformations should be used with caution. A couplet at about 520 cm–1 in the spectrum of the trifluoromethyl species may originate from the analogous trifluoromethyl asymmetric deformations.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Barron, Professor Laurence |
Authors: | Barron, L. D. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Journal of the Chemical Society: Perkin Transactions 2 |
Publisher: | Royal Society of Chemistry |
ISSN: | 1472-779X |
ISSN (Online): | 1364-5471 |
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