Magnetic optical activity in the resonance Raman spectra of metal halides: optical detection of ground-state Zeeman splittings

Barron, L.D. and Meehan, C. (1979) Magnetic optical activity in the resonance Raman spectra of metal halides: optical detection of ground-state Zeeman splittings. Chemical Physics Letters, 66(3), pp. 444-448. (doi: 10.1016/0009-2614(79)80313-9)

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Abstract

Magnetic optical activity has been observed in the resonance Raman spectra of dilute solutions of the odd-electron complexes IrCl2−6, FeBr−4 and CuBr2−4. The effects originate in “off-diagonal” transitions between the Zeeman levels of the Kramersalegenerate ground states. As well as providing a sensitive test for antisymmetric scattering and assisting vibrational bond assignments, the technique might give the g-factor.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Barron, Professor Laurence
Authors: Barron, L.D., and Meehan, C.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Physics Letters
Publisher:Elsevier
ISSN:0009-2614
ISSN (Online):1873-4448

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