Barron, L.D. and Escribano, J.R. (1986) Polarized raman optical activity of β-pinene: electric quadrupole contributions. Chemical Physics Letters, 126(5), 461 - 464. (doi: 10.1016/S0009-2614(86)80136-1)
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Abstract
A comparison of the polarized and depolarized Raman optical activity spectra of β-pinene, obtained with a new optical multichannel instrument, provides evidence for large electric-dipole-electric-quadrupole contributions. A consideration of the symmetry characteristics of the π★ ← π transition shows that such contributions are expected from deformations of an olefinic group with local C2v symmetry.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Barron, Professor Laurence |
| Authors: | Barron, L.D., and Escribano, J.R. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Physics Letters |
| Publisher: | Elsevier Science |
| ISSN: | 0009-2614 |
| ISSN (Online): | 1873-4448 |
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