Adams, D. J. , Clark, J. H., Hansen, L. B., Sanders, V. C. and Tavener, S. J. (1998) Reaction of tetramethylammonium fluoride with trifluoromethyltrimethylsilane. Journal of Fluorine Chemistry, 92(2), pp. 123-125. (doi: 10.1016/S0022-1139(98)00273-5)
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Abstract
Tetramethylammonium fluoride reacts with either triluoromethyltrimethylsilane or trimethylsilylacetonitrile in acetonitrile to form a pentacoordinate silicon species, which can act as a source of either fluoride or cyanomethyl carbanion, depending on substrate.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Adams, Dave |
Authors: | Adams, D. J., Clark, J. H., Hansen, L. B., Sanders, V. C., and Tavener, S. J. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Journal of Fluorine Chemistry |
Publisher: | Elsevier |
ISSN: | 0022-1139 |
ISSN (Online): | 1873-3328 |
Published Online: | 07 January 2000 |
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