Reaction of tetramethylammonium fluoride with trifluoromethyltrimethylsilane

Adams, D. J. , Clark, J. H., Hansen, L. B., Sanders, V. C. and Tavener, S. J. (1998) Reaction of tetramethylammonium fluoride with trifluoromethyltrimethylsilane. Journal of Fluorine Chemistry, 92(2), pp. 123-125. (doi: 10.1016/S0022-1139(98)00273-5)

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Abstract

Tetramethylammonium fluoride reacts with either triluoromethyltrimethylsilane or trimethylsilylacetonitrile in acetonitrile to form a pentacoordinate silicon species, which can act as a source of either fluoride or cyanomethyl carbanion, depending on substrate.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Adams, Dave
Authors: Adams, D. J., Clark, J. H., Hansen, L. B., Sanders, V. C., and Tavener, S. J.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of Fluorine Chemistry
Publisher:Elsevier
ISSN:0022-1139
ISSN (Online):1873-3328
Published Online:07 January 2000

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