Adams, D. J. , Clark, J. H., McFarland, H. and Nightingale, D. J. (1999) Unexpected side products in the tetramethylammonium fluoride–dimethylsulphoxide system. Journal of Fluorine Chemistry, 94(1), pp. 51-55. (doi: 10.1016/S0022-1139(98)00338-8)
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Abstract
Reactions of chloro- and nitro-aromatics with low water content solutions of TMAF in DMSO can lead to complex product mixtures resulting from activation of DMSO by fluoride and the formation of DMSO-derived products. Also, the system has been shown to give hydrolysis products in addition to the well-known ethers and phenols, with carboxylic acids and benzamides being formed from the attempted fluorodenitration of substituted benzonitriles.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Adams, Dave |
| Authors: | Adams, D. J., Clark, J. H., McFarland, H., and Nightingale, D. J. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Journal of Fluorine Chemistry |
| Publisher: | Elsevier |
| ISSN: | 0022-1139 |
| ISSN (Online): | 1873-3328 |
| Published Online: | 10 March 1999 |
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