Adams, D. J. , Chen, W., Hope, E. G., Lange, S., Stuart, A. M., West, A. and Xiao, J. (2003) Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(iii) ligands in supercritical CO2 and CH2Cl2. Green Chemistry, 5(2), pp. 118-122. (doi: 10.1039/B212313B)
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Abstract
Four chiral perfluoroalkylated monodentate phosphorus(III) ligands have been prepared and characterised. These ligands have been evaluated in the rhodium-catalysed asymmetric hydrogenation of dimethyl itaconate in both dichloromethane and supercritical CO2 (scCO2) and compared with the parent, non-perfluoroalkylated, catalyst systems.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Adams, Dave |
Authors: | Adams, D. J., Chen, W., Hope, E. G., Lange, S., Stuart, A. M., West, A., and Xiao, J. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Green Chemistry |
Publisher: | Royal Society of Chemistry |
ISSN: | 1463-9262 |
ISSN (Online): | 1463-9270 |
Published Online: | 27 March 2003 |
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