Adams, D. J. , Cole-Hamilton, D. J., Harding, D. A.J., Hope, E. G., Pogorzelec, P. and Stuart, A. M. (2004) Towards the synthesis of perfluoroalkylated derivatives of Xantphos. Tetrahedron, 60(18), pp. 4079-4085. (doi: 10.1016/j.tet.2004.02.070)
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Abstract
An analogue of Xantphos incorporating four perfluoroalkyl groups has been prepared and successfully used as a ligand in the rhodium-catalysed hydroformylation of 1-octene in toluene. A number of perfluoroalkylated xanthene backbones have also been synthesised, but their conversion into preferentially perfluorocarbon solvent soluble Xantphos-type ligands, suitable for catalysis in fluorocarbon solvents, has not been successful.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Adams, Dave |
Authors: | Adams, D. J., Cole-Hamilton, D. J., Harding, D. A.J., Hope, E. G., Pogorzelec, P., and Stuart, A. M. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Tetrahedron |
Publisher: | Elsevier |
ISSN: | 0040-4020 |
ISSN (Online): | 0040-4020 |
Published Online: | 08 April 2004 |
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