Holst, J. R., Stöckel, E., Adams, D. J. and Cooper, A. I. (2010) High surface area networks from tetrahedral monomers: metal-catalyzed coupling, thermal polymerization, and “click” chemistry. Macromolecules, 43(20), pp. 8531-8538. (doi: 10.1021/ma101677t)
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Abstract
A series of tetrahedrally linked conjugated microporous polymer networks were prepared using a variety of bond-forming chemistries including Sonogashira−Hagihara coupling, Yamamoto coupling, thermal alkyne condensation, and “click” chemistry. These thermally stable polymers exhibit high surface areas (up to 3200 m2/g) and adsorb up to 2.34 wt % hydrogen by mass at 1.13 bar/77 K and 7.59 wt % carbon dioxide by mass at 1.13 bar/298 K.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Adams, Dave |
Authors: | Holst, J. R., Stöckel, E., Adams, D. J., and Cooper, A. I. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Macromolecules |
Publisher: | American Chemical Society |
ISSN: | 0024-9297 |
ISSN (Online): | 1520-5835 |
Published Online: | 28 September 2010 |
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