Jiang, J.-X., Laybourn, A., Clowes, R., Khimyak, Y. Z., Bacsa, J., Higgins, S. J., Adams, D. J. and Cooper, A. I. (2010) High surface area contorted conjugated microporous polymers based on spiro-bipropylenedioxythiophene. Macromolecules, 43(18), pp. 7577-7582. (doi: 10.1021/ma101468r)
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Abstract
Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(2,5-dibromopropylenedioxythiophene) with one of three di- or triethynyl monomers. These polymers have surface areas up to 1631 m2/g and exhibit significant microporosity, suggesting possible applications in the fields of organic electronics or optoelectronics.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Adams, Dave |
| Authors: | Jiang, J.-X., Laybourn, A., Clowes, R., Khimyak, Y. Z., Bacsa, J., Higgins, S. J., Adams, D. J., and Cooper, A. I. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Macromolecules |
| Publisher: | American Chemical Society |
| ISSN: | 0024-9297 |
| ISSN (Online): | 1520-5835 |
| Published Online: | 17 August 2010 |
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