Jiang, S., Bacsa, J., Wu, X., Jones, J. T. A., Dawson, R., Trewin, A., Adams, D. J. and Cooper, A. I. (2011) Selective gas sorption in a [2+3] ‘propeller’ cage crystal. Chemical Communications, 47(31), pp. 8919-8921. (doi: 10.1039/C1CC12460A)
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Abstract
A [2+3] organic cage compound based on the condensation reaction of 1,3,5-tri(4-formylphenyl)benzene with 1,5-pentanediamine was synthesized. The resulting porous molecular crystal demonstrates selective adsorption of hydrogen and carbon dioxide over nitrogen. As for porous polymer membranes, a trade-off between sorption capacity and selectivity is observed for materials in this class.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Adams, Dave |
| Authors: | Jiang, S., Bacsa, J., Wu, X., Jones, J. T. A., Dawson, R., Trewin, A., Adams, D. J., and Cooper, A. I. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 10 June 2011 |
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