Mitra, T., Wu, X., Clowes, R., Jones, J. T. A., Jelfs, K. E., Adams, D. J. , Trewin, A., Bacsa, J., Steiner, A. and Cooper, A. I. (2011) A soft porous organic cage crystal with complex gas sorption behavior. Chemistry: A European Journal, 17(37), pp. 10235-10240. (doi: 10.1002/chem.201101631) (PMID:21837691)
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Abstract
Big softy! A soft porous molecular crystal composed of organic cages exhibits complex multistep gas sorption isotherms (see figure), analogous to those observed in soft porous metal–organic frameworks. Softness is induced by frustrated packing of the cages and structural flexibility leads to kinetic guest trapping.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Adams, Dave |
| Authors: | Mitra, T., Wu, X., Clowes, R., Jones, J. T. A., Jelfs, K. E., Adams, D. J., Trewin, A., Bacsa, J., Steiner, A., and Cooper, A. I. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemistry: A European Journal |
| Publisher: | Wiley |
| ISSN: | 0947-6539 |
| ISSN (Online): | 1521-3765 |
| Published Online: | 11 August 2011 |
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