Atanasov, M., Busche, C. , Comba, P., El Hallak, F., Martin, B., Rajaraman, G., van Slageren, J. and Wadepohl, H. (2008) Trinuclear {M1}CN{M2}2 complexes (M1= CrIII, FeIII, CoIII; M2= CuII, NiII, MnII). Are single molecule magnets predictable? Inorganic Chemistry, 47(18), pp. 8112-8125. (doi: 10.1021/ic800556c) (PMID:18714990)
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Abstract
The structures and magnetic properties of a series of hexacyanometalate-based trinuclear complexes with linear or bent geometries is analyzed with an orbital-dependent extended Heisenberg Hamiltonian. The absence of SMM behavior is shown to be due to the large angular distortions of the hexacyanoferrate centers.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Busche, Dr Christopher |
| Authors: | Atanasov, M., Busche, C., Comba, P., El Hallak, F., Martin, B., Rajaraman, G., van Slageren, J., and Wadepohl, H. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Inorganic Chemistry |
| Publisher: | American Chemical Society |
| ISSN: | 0020-1669 |
| ISSN (Online): | 1520-510X |
| Published Online: | 21 August 2008 |
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