Leigh, D. A. and Thomson, A. R. (2006) Switchable dual binding mode molecular shuttle. Organic Letters, 8(23), pp. 5377-5379. (doi: 10.1021/ol062284j) (PMID:17078722)
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Abstract
Protonation controls the location of a dual binding mode macrocycle in a [2]rotaxane. In the neutral form, amide−amide hydrogen bonds hold the macrocycle over a dipeptide residue; when the thread is protonated, polyether−ammonium cation interactions dominate and the macrocycle changes position.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Thomson, Dr Drew |
Authors: | Leigh, D. A., and Thomson, A. R. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Organic Letters |
Publisher: | American Chemical Society |
ISSN: | 1523-7060 |
ISSN (Online): | 1523-7052 |
Published Online: | 11 October 2006 |
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