On the nature of cracks and voids in nuclear graphite

Freeman, H.M., Jones, A.N., Ward, M.B., Hage, F.S., Tzelepi, N., Ramasse, Q.M., Scott, A.J. and Brydson, R.M.D. (2016) On the nature of cracks and voids in nuclear graphite. Carbon, 103, pp. 45-55. (doi: 10.1016/j.carbon.2016.03.011)

Abstract

Microcracks in neutron-irradiated nuclear grade graphite have been examined in detail for the first time using a combination of transmission electron microscopy (TEM), electron energy loss spectroscopy (EELS), energy dispersive X-ray (EDX), and energy filtered TEM (EFTEM). Filler particles from both unirradiated Pile Grade A (PGA) and three irradiated British Experimental Pile ‘O’ (BEPO) graphite specimens were investigated with received doses ranging from 0.4 to 1.44 displacements per atom (dpa) and an irradiation temperature of between 20 and 120 °C. We suggest that the concentration and potentially the size of microcracks increase with increasing neutron irradiation and show that disordered carbon material is present in a range of microcracks (of varying size and shape) in all specimens including unirradiated material. EFTEM and EELS data showed that these cracks contained carbon material of lower density and graphitic character than that of the surrounding bulk graphite. The presence of partially filled microcracks has potentially significant implications for the development of microstructural models for the prediction of radiation-induced dimensional and property changes in nuclear graphite.

• Item Type: Articles
• Additional Information: Funding was provided by the National Nuclear Laboratory and EPSRC (EP/J502042/1, EP/I003169/1). We gratefully acknowledge the Leeds EPSRC Nanoscience and Nanotechnology Facility (grant EP/K023853/1) for TEM and SAED. We thank Jean-Pierre Da Costa and the late Patrick Weisbecker for provision of the HRTEM analysis software through the program ‘‘PyroMaN’’ (grant ANR-BLAN-2010- 0929) supported by the ANR agency.
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Hage, Dr Fredrik Sydow
• Authors: Freeman, H.M., Jones, A.N., Ward, M.B., Hage, F.S., Tzelepi, N., Ramasse, Q.M., Scott, A.J., and Brydson, R.M.D.
• College/School: College of Science and Engineering > School of Physics and Astronomy
• Journal Name: Carbon
• Publisher: Elsevier
• ISSN: 0008-6223
• Published Online: 03 March 2016
• Copyright Holders: Copyright © 2016 Elsevier Ltd.
• First Published: First published in Carbon 103: 45-55
• Publisher Policy: Reproduced in accordance with the publisher copyright policy