Clark, J. S., Hayes, S. T., Wilson, C. and Gobbi, L. (2007) A concise total synthesis of (+/-)-vigulariol. Angewandte Chemie (International Edition), 46(3), pp. 437-440. (doi: 10.1002/anie.200603880)
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Publisher's URL: http://dx.doi.org/10.1002/anie.200603880
Abstract
<b>From the deep:</b> Vigulariol has been efficiently synthesized in 20 steps and 4.0 % overall yield from commercially available starting materials. Key to the synthesis was the use of copper(II) hexafluoroacetylacetate [Cu(hfacac)<sub>2</sub>] to form the oxabicyclo[6.2.1]undecene system (see scheme; TBS=tert-butyldimethylsilyl). The strategy should provide access to other members of the cladiellin family.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Clark, Professor Stephen and Wilson, Professor Charles |
Authors: | Clark, J. S., Hayes, S. T., Wilson, C., and Gobbi, L. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Angewandte Chemie (International Edition) |
Journal Abbr.: | Angew. Chem. Int. Ed. Engl. |
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA |
ISSN: | 1433-7851 |
ISSN (Online): | 1521-3773 |
Published Online: | 05 December 2006 |
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