Takashima, Y., Miras, H. N. , Glatzel, S. and Cronin, L. (2016) Shrink wrapping redox-active crystals of polyoxometalate open frameworks with organic polymers via crystal induced polymerisation. Chemical Communications, 52(50), pp. 7794-7797. (doi: 10.1039/C6CC03031A) (PMID:27203804) (PMCID:PMC6055993)
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Abstract
We report examples of crystal surface modification of polyoxometalate open frameworks whereby the use of pyrrole or aniline as monomers leads to the formation of the corresponding polymers via an oxidative polymerization process initiated by the redox active POM scaffolds. Guest-exchange experiments demonstrate that the polymers can finely tune the guest exchange rate and their structural integrity is retained after the surface modifications. In addition, the formation of polyoxometalate-based self-fabricating tubes by the dissolution of Keggin-based network crystals were also modulated by the polymers, allowing a new type of hybrid inorganic polymer with an organic coating to be fabricated.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos and Cronin, Professor Lee and Takashima, Dr Yohei and Glatzel, Dr Stefan |
Authors: | Takashima, Y., Miras, H. N., Glatzel, S., and Cronin, L. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Chemical Communications |
Publisher: | Royal Society of Chemistry |
ISSN: | 1359-7345 |
ISSN (Online): | 1364-548X |
Published Online: | 10 May 2016 |
Copyright Holders: | Copyright © 2016 The Royal Society of Chemistry |
First Published: | First published in Chemical Communications 52(50): 7794-7797 |
Publisher Policy: | Reproduced in accordance with the publisher copyright policy |
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